Effect of microstructure on hydrogeninduced cracking of. Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Hydrogeninduced cracking is also known as cold cracking, delayed cracking or underbead cracking. The significance of these failures has led to research aimed at defining critical conditions for hisc, to allow confident design of components in future. Elements hic tests evaluate material susceptibility to hydrogen induced cracking in a sour environment in accordance with nace tm0284.
Abstract hydrogeninduced cracking hic has been studied phenomenologically. Hydrogen induced cracking test metallurgical services. Therefore, it is used throughout this standard test method. Corrosion loops were established for the sour environment and revealed that hic is one of the potential damage mechanisms that could affect the sour gas system. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. Hydrogen induced cracking hic testing of low alloy steel in sour. Hic steel hydrogen induced cracking supplier company. Sour gas h2s testing of dicrest hic resistant steel plates using test solution a the most common grades of hic resistant steel plate is a516 to asmeastm standards. Abstract hydrogen induced cracking hic has been studied phenomenologically. It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses. Hic is susceptible to be presented in the sour gas system because of the. It was not until much later, however, that hic started to be investigated and gained recognition as a potential problem in pipelines as a result of pipeline failures.
Hydrogen induced cracking hic and the blistering of carbon steel are both such unexpected corrosion phenomenon. To evaluate their resistance to hic, two flasks were used for each test, one. Sour gas h2s testing of dicrest hic resistant steel plates using test solution a the most common grades of hic resistant. Hic steel is plate which is tested to reduce the effects of hydrogen induced cracking in a wet h2s or sour service environment. A comparative study of hydrogeninduced cracking resistances of. Atomic hydrogen, and not the molecule, is the smallest atom and it is small enough to diffuse readily through a metallic structure. Hydrogen blistering a special case of hydrogen damage is known as hydrogen blistering. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated.
Tcr engineering services corrosion testing laboratory performs hic test to evaluate the resistance of pipelines, pressure vessel plate steels and hydrogeninduced cracking caused by hydrogen absorption from aqueous sulfide corrosion. This page introduced the hydrogeninduced crackinghic in ferrous and nonferrous metals including the definition and mechanism of hic, as well as the hic test in accordance with nace tm0284. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen absorption from aqueous sulfide corrosion. The presence of hydrogen in the weld metal or haz may lead to a form of cracking known as hydrogeninduced cracking hic.
Hydrogen induced cracking hic is a common form of wet h2s cracking caused. Hydrogen induced cracking hic there are several categories of hydrogen phenomena that are localized in nature. The effect of microstructure on hic is discussed for steels having two different levels of nonmetallic inclusions. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Environmental cracking is a general term that includes. Hydrogeninduced cracking hic is a far too common type of failure. The term hydrogeninduced cracking hic has been widely used for describing cracking of this type, and has been adopted by nace international.
The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Processes or conditions involving wet hydrogen sulfide, i. Essentially, the hic test actually tests a sample of steel for its susceptibility to hydrogen embrittlement. If you recall, we mentioned you need all three factors to be present in order to have hic. Hydrogen induced cracking hic is a mechanical fracture caused by the penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular hydrogen in the internal interface between nonmetallic inclusion and base material. Sulfide stress cracking ssc vs hydrogen induced cracking hlc. Hydrogen induced cracking hic of line pipe steel was investigated through immersion testing and hydrogen permeation measurements. Hydrogen induced cracking test tank test methods nace tm0284 astm g39 material of construction polypropylene, pvc, or glass capacities up to 55 liters cortest offers a variety of different hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on a metal sample in a hydrogen enriched. Some of the examples are resistance to hydrogen sulphide h2s cracking such as sulphide stress cracking ssc, stress oriented hydrogen induced cracking sohic, hydrogen induced cracking hic, step wise cracking swc, soft zone cracking szc etc. The steps of a possible mechanism of hydrogen induced cracking hic can be, first, interstitial diffusion of hydrogen atoms under the steel surface. Hydrogen induced cracking hic when atomic hydrogen diffuses into the metallic structure, as described for ssc, if the material contains large quantities of inclusions, particularly elongated. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Nace international has adopted the term hydrogen induced cracking hic. Hydrogen induced cracking hic testing of low alloy steel in.
Unfortunately, the term hydrogeninduced cracking, usually abbreviated as hic, has been introduced to designate cracking sometimes encountered in pipelines or vessels as a result of hydrogen picked up in. Hydrogen blistering occurs when hydrogen atoms diffuse into the steel, and hydrogen gas nucleates at internal defects and inclusions, forming voids which eventually generate enough pressure to locally rupture the metal. Naceastm g1931 includes the following description of. The presence of hydrogen in the weld metal or haz may lead to a form of cracking known as hydrogen. Hydrogen combines with carbon within the alloy and forms methane. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogen induced cracking hic, describes the embrittling of metal after being exposed to hydrogen. The steps of a possible mechanism of hydrogeninduced cracking hic can be. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. This page introduced the hydrogeninduced cracking hic in ferrous and nonferrous metals including the definition and mechanism of hic, as well as the hic test in accordance with nace tm0284. Ansinace tm02842016, evaluation of pipeline and pressure vessel steels for resistance to hydrogeninduced cracking available for download test conditions for evaluation of pipeline and pressure vessel steels.
When the crystal lattice is in contact or is saturated with atomic hydrogen, the mechanical. The tests are performed in accordance with iso 15156 nace mr0175. Sulfide stress cracking ssc vs hydrogen induced cracking. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogen induced cracking hic, sulphide stress cracking ssc and stressoriented hydrogen induced cracking sohic. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. Hydrogen induced cracking steel features, applications and. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms.
The tests are normally carried out according to nace tm0284. Hydrogen induced cracking hic testing of low alloy steel. Regular inspection and testing should be performed in order to eliminate the. We will now go over how to prevent hic from happening. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. Hydrogen induced cracking hic causes and prevention. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. This form of cracking is also commonly referred to. Factors influencing hydrogen induced cracking welding. Hydrogeninduced cracking an overview sciencedirect topics. Ansinace tm02842016, evaluation of pipeline and pressure. May 22, 2018 hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan.
Stressoriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking. Nace international has adopted the term hydrogeninduced cracking hic. It is also called hydrogen assisted cracking hac and delayed cracking since it does not occur right after welding, but a few hours or days after the weld has completely cooled down to ambient temperature. Hydrogeninduced cracking susceptibility in highstrength. In essence, hic testing is actually an evaluation of the steel for susceptibility to hydrogen embrittlement. Hydrogen embrittlement involves the ingress of hydrogen into a component e.
Our last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking. The test procedure involves the evaluation of resistance of pressure vessel steel plate and pipework steels to hydrogen reduced cracking caused by hydrogen absorption from aqueous sulfide corrosion. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. The steps of a possible mechanism of hydrogeninduced cracking hic can be, first, interstitial diffusion of hydrogen atoms under the steel surface. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen. It occurs at a rate that depends on the packaging of the iron unit cell, that is, greater diffusibility in the ferrite phase bcc than in the more compact austenite phase fcc. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. Weld metal cracking hydrogen cracking induced cracking crack susceptibility saw cracking tests basic bonded flux diffusible hydrogen flux bake temperature critical temperature 100140 ksi steel in this investigation, the hic susceptibil ity of multipass hightensile strength weld metals ranging from 70 to 100 kgfmm2. A comparative study of hydrogeninduced cracking resistances. Astm f519 hydrogen embrittlement he testing element. Hydrogen induced cracking hic laboratory testing assessment. Hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Cortest offers hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on metal samples in hydrogen enriched aqueous environments such as those in h 2 ssour service applications.
Unstressed test specimens are exposed to a solution at temperature of 25deg cent with continuous h2s gas flow. Hydrogen damage figure 1 is encountered in many steel processes, such as pickling, electroplating and welding. Preventing hydrogen induced cracking welding answers. Hydrogen blistering has been recognized since the 1940s as a problem in vessel handling sour products. Hydrogen induced cracking hic from advanced ndt solutions. Hydrogen induced cracking hic laboratory testing assessment of low alloy steel linepipe. Hic resistant steel plate is used by boiler makers and fabricators when hydrogen induced cracking is a big risk.
Cortest offers hydrogen induced cracking hic test tank designs that can be used to study the corrosive and embrittling effects on metal samples in hydrogen enriched aqueous environments such as those in h 2 ssour service applications hic tanks are suitable for samples specified in nace tm0284 as well as 3 and 4 point bend fixtures specified in both nace tm0177 and. Hydrogeninduced cracking hic tests should be performed and reported in accordance with nace tm 028496. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from. Tcr engineering mumbai corrosion testing, nace, astm. Naceastm g193 1 includes the following description of hydrogen blistering. As we know that both form of cracking are due to the absorption of atomic hydrogen that. Corrosionpedia what is hydrogeninduced cracking hic. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after.
Factors influencing hydrogen induced cracking welding answers. Hic hydrogen induced cracking, ssc sulphide stress cracking, scc stress corrosion cracking sohic. Cracking occurs due to a significant loss in ductility. Hic test, hydrogen induced cracking test, step wise. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogeninduced cracking hic, sulphide stress cracking ssc and stressoriented hydrogeninduced cracking sohic. Element performs hydrogen embrittlement he testing to astm f519, galvanically induced hydrogen stress cracking ghsc to nace mr0175iso 15156 and hydrogen induced stress cracking hisc testing. O ur last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking. Hydrogen induced cracking test for naval steels youtube. This paper describes the work conducted at the british gas engineering research station ers using laboratory tests of the bp and nace type to assess the hydrogen induced cracking hic resistance of pipeline steels. Apr 14, 2020 hydrogen induced cracking hic when atomic hydrogen diffuses into the metallic structure, as described for ssc, if the material contains large quantities of inclusions, particularly elongated. Hydrogen induced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement.
The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure. This form of cracking is also commonly referred to as hydrogen. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. At constant ph and hydrogen sulphide partial pressure ph 2 s, the extent of hic was found to depend on exposure time until a stable level was reached. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hydrogen induced cracking in pipeline steels corrosion. Hydrogen induced cracking steel features, applications.
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